rr not being its own letter has no bearing on if you can pronounce carro correctly, just like saying church right has no bearing on if c and h are two letters or ch is a single letter.
I'm afraid that I have to add my voice to the list of people raised in Spanish speaking countries prior to the 90s who was VERY clearly taught that rr was a separate letter.
In Spanish "rr" has never been considered as a single letter. "Ch" and "ll" used to be, but not anymore. Ñ is, of course.